中国半导体行业协会封装分会会刊

中国电子学会电子制造与封装技术分会会刊

导航

电子与封装 ›› 2021, Vol. 21 ›› Issue (4): 040201 . doi: 10.16257/j.cnki.1681-1070.2021.0403

• 封装、组装与测试 • 上一篇    下一篇

进口AuSn20焊料环特性及焊缝化合物分析*

马艳艳1;赵鹤然1;康敏1;李莉莹2;曹丽华3   

  1. 1. 中国电子科技集团公司第四十七研究所,沈阳 110032;2. 沈阳农业大学信息与电气工程学院,沈阳 110866;3. 中国科学院金属研究所,沈阳 110016
  • 收稿日期:2020-10-12 出版日期:2021-04-27 发布日期:2020-11-16
  • 作者简介:马艳艳(1988—),女,内蒙古人,硕士研究生,工程师,主要研究方向为微系统技术与可靠性;

Analysisof Imported AuSn20 Solder Ring Characteristics and Weld Compound

MA Yanyan1, ZHAO Heran1, KANG Min1, LI Liying2, CAO Lihua3   

  1. 1. The 47th Institute of China Electronics Technology Group Corporation, Shenyang 110032, China; 2. School of Information and Electrical Engineering, Shenyang Agricultural University, Shenyang 110866, China; 3. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
  • Received:2020-10-12 Online:2021-04-27 Published:2020-11-16

摘要: AuSn20焊料环是高可靠密封工艺中一种常用的密封材料,采用差示扫描量热法对进口AuSn20焊料环进行熔化和凝固温度的检测,探明其熔化温度为280 ℃,凝固温度为277 ℃,纯度很高几乎无杂质。对比了进口和国产AuSn20焊料环的表面状态形貌,均为AuSn和Au5Sn的均匀分布状态,未见明显区别。采用进口AuSn20焊料密封电路,通过研磨、抛光等步骤,制备了焊缝区域截面,并观察了截面微观形貌,通过能谱分析探测了截面上的元素成分,结合金锡二元相图,确定共晶反应后焊缝区域化合物以AuSn和Au5Sn为主,同时观察到管壳、盖板与焊料环界面上形成了(Ni,Au)3Sn2,并进一步推演了AuSn20焊料密封反应过程。

关键词: 金锡合金, 密封, 界面金属化合物, 焊料

Abstract: AuSn20 solder ring is a commonly used sealing material in high-reliability sealing process. Using differential scanning calorimetry to detect the melting and solidification temperature of the imported AuSn20 solder ring, it is proved that the melting temperature is 280 ℃, the solidification temperature is 277 ℃, the purity is very high and almost no impurities. The surface state and morphology of the imported and domestic AuSn20 solder rings are compared. They are both the uniform distribution state of AuSn and Au5Sn, and there is no obvious difference. The imported AuSn20 solder was used to seal the circuit, and after grinding and polishing, the section of the weld area was prepared, and the microscopic morphology of the section was observed. The element composition on the cross-section was detected by energy spectrum analysis, combined with the binary phase of gold and tin, it was determined that AuSn and Au5Sn were the main compounds in the weld area after the eutectic reaction. At the same time, it was observed that the interface between the shell, cover and solder ring formed (Ni,Au)3Sn2. Furthermore, the AuSn20 solder sealing reaction is deduced.

Key words: gold-tinalloy, sealing, intermetalliccompounds, solder

中图分类号: